Uncanny Web-Slinger
Super Freak
But none of those are Avengers comics...
There you go...you've only been reading since HoM, you read on and off, and no main Avengers comics, he's an Avengers villain. So you missed his stories, that's all.
Gotcha, but since he's not been in (m)any of the big events, he's hardly an A-Lister in the Marvel Universe.
It would seem he's an A-Lister for the Avengers series but not for the universe as a whole like Norman Osborn is.
He looks to be very self contained, at the level of Electro or Sebastian Shaw, a key villlain for the appropriate hero/title but not a villain that's dealt with lots of different heroes in different books enough to be known universe wide, like Galactus is.
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