Count me as one of those people. It's about bang for the buck...and it's also about getting the best version of a character. If you're trying to get a lineup of all the characters exactly as they appeared in CW, then this one's for you! But HT is known to put out better and better versions of a character as they go along, adding more value as they reuse existing parts. Cap CW comes with the extra teeth sculpt over AoU, for example. The standalone movie BP will probably come with a new sculpt, Marvel will probably refine the costume some, it'll probably be closest to how he'll appear in future movies (that's just taking the previous experience with Thor, BW, and Cap into account), and HT will add some extras - hands, maybe an accessory or two if the movie warrants, and definitely a headsculpt. Might as well wait and get a bit more payoff.
Besides, for me at least, I've already got 3 other figures on PO from CW. Deciding to wait until the solo films for Spidey and BP spreads my money out a bit better than cramming it in all at once and not saving anything for later.
That's not to say I won't consider it. If he ends up on some sort of mega sale down the road after I'm done paying off the other figures (that's how I ended up with WS Bucky instead of waiting for the CW version), I'd pick him up. I doubt he'll stay available that long, but weirder things have happened - I've always been surprised at how long WS Falcon was available.