Honestly, you will have to put more work into it than simply sitting in front of your computer and receiving replies from other posters. If you're not willing to make multiple purchases, let me warn you off the whole thing right now. Give up and don't bother, this isn't for you.
Now, that said, everything can be bought from eBay from different sellers.
Those are two brands of 1/6 clothing. Both brands make Tuxedos, Toys City being by far the higher quality and better fitting of the two. Available as mentioned, on eBay or online stores like BBTS.
The Very Cool will need a slim body to fit. The Toys City will work on a Hot Toys TTM Narrow Shoulder or Advanced/Regular (TTM21) however, the Advanced and newer Regular feature bigger upper arms which make the jacket a bit too tight and form-fitting. I think the best option here is probably the Narrow Shoulder variety which is essentially the same body with smaller arms - you can find knock-offs on eBay for $25. The Agent Coulson body seems similar, but you're likely to pay a premium for any Hot Toys character-specific body.
You can read back a couple of months in this thread, it's not very much, and help yourself.