Honestly, I would probably most prefer Sandman because he would be most comic accurate. Then Doc Ock because of the complexity and potential awesomeness of the tentacles. Third for me would be Venom, because he would look pretty cool on the shelf, despite sucking horribly in the movie. Fourth would be Green Goblin V.1, who would be higher as a character, but I never cared much for the weird armored, helmeted look. Would probably still buy though because he's Spidey's primary villain. Fifth would be JJJ, sixth would be guy Spidey thought shot Uncle Ben in the first film, seventh would be Bonesaw, eight would be armless Curt Connors (even though he never actually turned into Lizard in those films), ninth would be generic thug who tried to rape Mary Jane, and New Goblin would be 10th with a bullet.Doc Ock has got to be at the top